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Solvent engineering for scalable fabrication of perovskite/silicon tandem solar cells in air.
Zheng, Xuntian; Kong, Wenchi; Wen, Jin; Hong, Jiajia; Luo, Haowen; Xia, Rui; Huang, Zilong; Luo, Xin; Liu, Zhou; Li, Hongjiang; Sun, Hongfei; Wang, Yurui; Liu, Chenshuaiyu; Wu, Pu; Gao, Han; Li, Manya; Bui, Anh Dinh; Mo, Yi; Zhang, Xueling; Yang, Guangtao; Chen, Yifeng; Feng, Zhiqiang; Nguyen, Hieu T; Lin, Renxing; Li, Ludong; Gao, Jifan; Tan, Hairen.
Afiliação
  • Zheng X; National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing, 210023, China.
  • Kong W; National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing, 210023, China. kongwenchi@nju.edu.cn.
  • Wen J; National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing, 210023, China.
  • Hong J; National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing, 210023, China.
  • Luo H; National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing, 210023, China.
  • Xia R; State Key Laboratory of PV Science and Technology, Trina Solar, ChangZhou, 210031, China.
  • Huang Z; National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing, 210023, China.
  • Luo X; National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing, 210023, China.
  • Liu Z; National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing, 210023, China.
  • Li H; State Key Laboratory of PV Science and Technology, Trina Solar, ChangZhou, 210031, China.
  • Sun H; National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing, 210023, China.
  • Wang Y; National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing, 210023, China.
  • Liu C; National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing, 210023, China.
  • Wu P; National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing, 210023, China.
  • Gao H; National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing, 210023, China.
  • Li M; National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing, 210023, China.
  • Bui AD; Research School of Electrical, Energy and Materials Engineering, College of Engineering and Computer Science, The Australian National University, Canberra, NSW, Australia.
  • Mo Y; State Key Laboratory of PV Science and Technology, Trina Solar, ChangZhou, 210031, China.
  • Zhang X; State Key Laboratory of PV Science and Technology, Trina Solar, ChangZhou, 210031, China.
  • Yang G; State Key Laboratory of PV Science and Technology, Trina Solar, ChangZhou, 210031, China.
  • Chen Y; State Key Laboratory of PV Science and Technology, Trina Solar, ChangZhou, 210031, China.
  • Feng Z; State Key Laboratory of PV Science and Technology, Trina Solar, ChangZhou, 210031, China.
  • Nguyen HT; Research School of Electrical, Energy and Materials Engineering, College of Engineering and Computer Science, The Australian National University, Canberra, NSW, Australia.
  • Lin R; National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing, 210023, China.
  • Li L; National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing, 210023, China.
  • Gao J; State Key Laboratory of PV Science and Technology, Trina Solar, ChangZhou, 210031, China. jifan.gao@trinasolar.com.
  • Tan H; National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing, 210023, China. hairentan@nju.edu.cn.
Nat Commun ; 15(1): 4907, 2024 Jun 08.
Article em En | MEDLINE | ID: mdl-38851760
ABSTRACT
Perovskite/silicon tandem solar cells hold great promise for realizing high power conversion efficiency at low cost. However, achieving scalable fabrication of wide-bandgap perovskite (~1.68 eV) in air, without the protective environment of an inert atmosphere, remains challenging due to moisture-induced degradation of perovskite films. Herein, this study reveals that the extent of moisture interference is significantly influenced by the properties of solvent. We further demonstrate that n-Butanol (nBA), with its low polarity and moderate volatilization rate, not only mitigates the detrimental effects of moisture in air during scalable fabrication but also enhances the uniformity of perovskite films. This approach enables us to achieve an impressive efficiency of 29.4% (certified 28.7%) for double-sided textured perovskite/silicon tandem cells featuring large-size pyramids (2-3 µm) and 26.3% over an aperture area of 16 cm2. This advance provides a route for large-scale production of perovskite/silicon tandem solar cells, marking a significant stride toward their commercial viability.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Nat Commun Assunto da revista: BIOLOGIA / CIENCIA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: China

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Nat Commun Assunto da revista: BIOLOGIA / CIENCIA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: China