Achieving "Ion Diode" Salt Resistance in Solar Interfacial Evaporation by a Tesla Valve-Like Water Transport Structure.

ABSTRACT

Salt deposition is a disturbing problem that limits the development of passive solar-driven interfacial evaporation. Inspired by the passive fluid control mechanism of the Tesla valve, a novel solar evaporator is proposed with a Tesla valve-like water transport structure to prevent salt accumulation at the evaporation interface. A unique "ion diode" salt resistance of this evaporator is significantly achieved by optimizing the two asymmetric water transport structures, consisting of one Tesla valve-like side and one wide-leg side, which establish a reverse-suppressing and forward-accelerating water transport channel. In contrast to the limited ion migration of the typical symmetric solar evaporator, such a channel caused by the water/salt ions transport difference between two water supply structures, reinforces the water/salt ions supply on the wide-leg side, thus leading to an apparent unidirectional salt ions migration from the wide-leg side to bulk water through the Tesla valve-like side. Consequently, an evaporation rate of 3.25 kg m-2 h-1 and a conversion efficiency of 83.27% under 2 suns are achieved in 16 wt% NaCl solution. The development of the Tesla Valve-like evaporator provides a new perspective for solving salt deposition and realizing scalable applications of solar-driven interfacial evaporation.