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Synthesis and soft crystal structure-induced broad emission of (NH3C6H12NH3)InBr5·2H2O.
Biswas, Shuva; Mandal, Arnab; Swain, Diptikanta; Biswas, Kanishka.
Afiliação
  • Biswas S; New Chemistry Unit, International Centre for Materials Science and School of Advanced Materials, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Jakkur P. O., Bangalore 560064, India. kanishka@jncasr.ac.in.
  • Mandal A; New Chemistry Unit, International Centre for Materials Science and School of Advanced Materials, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Jakkur P. O., Bangalore 560064, India. kanishka@jncasr.ac.in.
  • Swain D; Institute of Chemical Technology-IndianOil Odisha Campus, Bhubaneswar 751013, India.
  • Biswas K; New Chemistry Unit, International Centre for Materials Science and School of Advanced Materials, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Jakkur P. O., Bangalore 560064, India. kanishka@jncasr.ac.in.
Chem Commun (Camb) ; 60(60): 7757-7760, 2024 Jul 23.
Article em En | MEDLINE | ID: mdl-38973621
ABSTRACT
We report a simple synthesis of a new lead-free zero-dimensional (0D) hybrid halide compound, (5P1)InBr5·2H2O [(5P1) = NH3C6H12NH3], which hosts isolated and distorted octahedra of [InBr5(H2O)]2-, surrounded by bulky asymmetric organic cations [(5P1)2+] and H2O molecules. The hybrid crystals exhibit broad self trapped excitonic (STE) emission due to strong anharmonic soft structure.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: Índia País de publicação: Reino Unido

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: Índia País de publicação: Reino Unido