Alloying One-Dimensional Coordination Polymers To Create Ductile Materials.
J Am Chem Soc
; 146(33): 23412-23416, 2024 Aug 21.
Article
em En
| MEDLINE
| ID: mdl-39134058
ABSTRACT
The preparation of coordination polymer (CP) alloys is demonstrated by the use of two meltable, one-dimensional crystal structures via melt-kneading. The polymer structures of the alloys are studied by synchrotron X-ray absorption and scattering, solid-state NMR spectroscopy, DSC, and viscoelastic measurements. Crystalline and amorphous domains and thermal properties (melting and glass transition) in the alloys depend on the ratio of the two constituent CPs. The glassy alloy composed of an equivalent amount of two CPs shows high plastic deformation properties, and the fracture point reaches 128% without a filler or compatibilizing agent, hence behaving as ductile materials.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
J Am Chem Soc
Ano de publicação:
2024
Tipo de documento:
Article
País de afiliação:
Tailândia