Confining WS2 hierarchical structures into carbon core-shells for enhanced sodium storage.

ABSTRACT

The growing demand for clean energy has heightened interest in sodium-ion batteries (SIBs) as promising candidates for large-scale energy storage. However, the sluggish reaction kinetics and significant volumetric changes in anode materials present challenges to the electrochemical performance of SIBs. This work introduces a hierarchical structure where WS2 is confined between an inner hard carbon core and an outer nitrogen-doped carbon shell, forming HC@WS2@NCs core-shell structures as anodes for SIBs. The inner hard carbon core and outer nitrogen-doped carbon shell anchor WS2, enhancing its structural integrity. The highly conductive carbon materials accelerate electron transport during charge/discharge, while the rationally constructed interfaces between carbon and WS2 regulate the interfacial energy barrier and electric field distribution, improving ion transport. This synergistic interaction results in superior electrochemical performance the HC@WS2@NCs anode delivers a high capacity of 370 mAh g-1 at 0.2 A/g after 200 cycles and retains261 mAh g-1 at 2 A/g after 2000 cycles. In a full battery with a Na3V2(PO4)3 cathode, the Na3V2(PO4)3//HC@WS2@NC full-cell achieves an impressive initial capacity of 220 mAh g-1 at 1 A/g. This work provides a strategic approach for the systematic development of WS2-based anode materials for SIBs.