Effects of Ti substitution by Zr, on the microstructure and hydrogen storage properties OF Ti2-xZrxCrV (x = 0.5, 1, 1.5, 2) alloys.
Heliyon
; 10(15): e35739, 2024 Aug 15.
Article
em En
| MEDLINE
| ID: mdl-39170160
ABSTRACT
The effect of the substitution of Ti by Zr on the crystal structure, microstructure, and first hydrogenation behavior of Ti2-xZrxCrV where X = 0.5, 1.0, 1.5, and 2.0 have been investigated. The samples were synthesized by arc-melting and characterized by X-ray diffraction, scanning electron microscopy, and energy-dispersive spectroscopy. The hydrogenation capacity was measured using a home-made Sieverts apparatus. Pure-Ti2CrV crystallizes in a body-centered cubic structure (BCC). Substitution of Ti by Zr leads to the appearance of a secondary phase, namely a C15 Laves phase for the Ti-containing samples, and C15 Laves phase plus a Zr-rich phase for the X = 2.0 sample. The substitution of Ti by Zr increased the lattice parameters in both phases for all samples. Increasing Zr content made the first hydrogenation faster but reduced the hydrogen capacity.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Heliyon
Ano de publicação:
2024
Tipo de documento:
Article
País de afiliação:
Canadá
País de publicação:
Reino Unido