Nanocrystal Heterostructures Based on Halide Perovskites and Metal Sulfides.
J Am Chem Soc
; 2024 Sep 30.
Article
em En
| MEDLINE
| ID: mdl-39344522
ABSTRACT
We report the synthesis of nanocrystal heterostructures composed of CsPbCl3 and PbS domains sharing an epitaxial interface. We were able to promote the growth of a PbS domain (in competition with the more commonly observed Pb4S3Cl2 one) on top of the CsPbCl3 domain by employing Mn2+ ions, the latter most likely acting as scavengers of Cl- ions. Complete suppression of the Pb4S3Cl2 domain growth was then achieved by additionally selecting an appropriate sulfur source (bis(trimethylsilyl)sulfide, which also acted as a scavenger of Cl- ions) and reaction temperature. In the heterostructures, emission from the perovskite domain was quenched, while emission from the PbS domain was observed, pointing to a type-I band alignment, as confirmed by calculations. These heterostructures, in turn, could be exploited to prepare second-generation heterostructures through selective ion exchange on the individual domains (halide ion exchange on CsPbCl3 and cation exchange on PbS). We demonstrate the cases of Cl- â Br- and Pb2+ â Cu+ exchanges, which deliver CsPbBr3-PbS and CsPbCl3-Cu2-xS epitaxial heterostructures, respectively.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
J Am Chem Soc
Ano de publicação:
2024
Tipo de documento:
Article
País de afiliação:
Itália
País de publicação:
Estados Unidos