A Self-Sensing and Self-Powered Wearable System Based on Multi-Source Human Motion Energy Harvesting.

Wearable devices play an indispensable role in modern life, and the human body contains multiple wasted energies available for wearable devices. This study proposes a self-sensing and self-powered wearable system (SS-WS) based on scavenging waist motion energy and knee negative energy. The proposed SS-WS consists of a three-degree-of-freedom triboelectric nanogenerator (TDF-TENG) and a negative energy harvester (NEH). The TDF-TENG is driven by waist motion energy and the generated triboelectric signals are processed by deep learning for recognizing the human motion. The triboelectric signals generated by TDF-TENG can accurately recognize the motion state after processing based on Gate Recurrent Unit deep learning model. With double frequency up-conversion, the NEH recovers knee negative energy generation for powering wearable devices. A model wearing the single energy harvester can generate the power of 27.01 mW when the movement speed is 8 km h-1, and the power density of NEH reaches 0.3 W kg-1 at an external excitation condition of 3 Hz. Experiments and analysis prove that the proposed SS-WS can realize self-sensing and effectively power wearable devices.

High-Resolution Magnetoelectric Sensor and Low-Frequency Measurement Using Frequency Up-Conversion Technique.

The magnetoelectric (ME) sensor is a new type of magnetic sensor with ultrahigh sensitivity that suitable for the measurement of low-frequency weak magnetic fields. In this study, a metglas/PZT-5B ME sensor with mechanical resonance frequency fres of 60.041 kHz was prepared. It is interesting to note that its magnetic field resolution reached 0.20 nT at fres and 0.34 nT under a DC field, respectively. In order to measure ultralow-frequency AC magnetic fields, a frequency up-conversion technique was employed. Using this technique, a limit of detection (LOD) under an AC magnetic field lower than 1 nT at 8 Hz was obtained, and the minimum LOD of 0.51 nT was achieved at 20 Hz. The high-resolution ME sensor at the sub-nT level is promising in the field of low-frequency weak magnetic field measurement technology.

Analysis of Influencing Parameters Enhancing the Plucking Efficiency of Piezoelectric Energy Harvesters.

The integration of energy harvesting systems into sensing technologies can result in novel autonomous sensor nodes, characterized by significant simplification and mass reduction. The use of piezoelectric energy harvesters (PEHs), particularly in cantilever form, is considered as one of the most promising approaches aimed at collecting ubiquitous low-level kinetic energy. Due to the random nature of most excitation environments, the narrow PEH operating frequency bandwidth implies, however, the need to introduce frequency up-conversion mechanisms, able to convert random excitation into the oscillation of the cantilever at its eigenfrequency. A first systematic study is performed in this work to investigate the effects of 3D-printed plectrum designs on the specific power outputs obtainable from FUC excited PEHs. Therefore, novel rotating plectra configurations with different design parameters, determined by using a design-of-experiment methodology and manufactured via fused deposition modeling, are used in an innovative experimental setup to pluck a rectangular PEH at different velocities. The obtained voltage outputs are analyzed via advanced numerical methods. A comprehensive insight into the effects of plectrum properties on the responses of the PEHs is attained, representing a new and important step towards the development of efficient harvesters aimed at a wide range of applications, from wearable devices to structural health monitoring systems.

Broadband Vibration-Based Energy Harvesting for Wireless Sensor Applications Using Frequency Upconversion.

Silicon-based kinetic energy converters employing variable capacitors, also known as electrostatic vibration energy harvesters, hold promise as power sources for Internet of Things devices. However, for most wireless applications, such as wearable technology or environmental and structural monitoring, the ambient vibration is often at relatively low frequencies (1-100 Hz). Since the power output of electrostatic harvesters is positively correlated to the frequency of capacitance oscillation, typical electrostatic energy harvesters, designed to match the natural frequency of ambient vibrations, do not produce sufficient power output. Moreover, energy conversion is limited to a narrow range of input frequencies. To address these shortcomings, an impacted-based electrostatic energy harvester is explored experimentally. The impact refers to electrode collision and it triggers frequency upconversion, namely a secondary high-frequency free oscillation of the electrodes overlapping with primary device oscillation tuned to input vibration frequency. The main purpose of high-frequency oscillation is to enable additional energy conversion cycles since this will increase the energy output. The devices investigated were fabricated using a commercial microfabrication foundry process and were experimentally studied. These devices exhibit non-uniform cross-section electrodes and a springless mass. The non-uniform width electrodes were used to prevent pull-in following electrode collision. Springless masses from different materials and sizes, such as 0.5 mm diameter Tungsten carbide, 0.8 mm diameter Tungsten carbide, zirconium dioxide, and silicon nitride, were added in an attempt to force collisions over a range of applied frequencies that would not otherwise result in collisions. The results show that the system operates over a relatively wide frequency range (up to 700 Hz frequency range), with the lower limit far below the natural frequency of the device. The addition of the springless mass successfully increased the device bandwidth. For example, at a low peak-to-peak vibration acceleration of 0.5 g (peak-to-peak), the addition of a zirconium dioxide ball doubled the device's bandwidth. Testing with different balls indicates that the different sizes and material properties have different effects on the device's performance, altering its mechanical and electrical damping.

A Gyroscope Nanogenerator with Frequency Up-Conversion Effect for Fitness and Energy Harvesting.

Converting the mechanical energy of human motion into electricity is considered an ideal energy supply solution for portable electronics. However, low-frequency human movement limits conversion efficiency of conventional energy harvesting devices, which is difficult to provide sustainable power for portable electronic devices. Herein, a fitness gyroscope nanogenerator (fg-NG) based on a triboelectric nanogenerator (TENG) and electromagnetic generator (EMG) is developed that can convert low-frequency wrist motion into high-frequency rotation by using the frequency up-conversion effect of the gyroscope. Remarkably, the fg-NG can reach a rotational speed of over 8000 rpm by hand, increasing the frequency by more than 280 times. The fg-NG can continuously and stably output a current of 17 mA and a voltage of 70 V at frequency of 220-230 Hz. The fg-NG is demonstrated to consistently power a hygrothermograph, smart bracelet, and mobile phone. Also, it can be applicated to a self-powered intelligent training system, showing its immense application potential in portable electronics and wireless Internet of Things devices.

Wearable Ball-Impact Piezoelectric Multi-Converters for Low-Frequency Energy Harvesting from Human Motion.

Multi-converter piezoelectric harvesters based on mono-axial and bi-axial configurations are proposed. The harvesters exploit two and four piezoelectric converters (PCs) and adopt an impinging spherical steel ball to harvest electrical energy from human motion. When the harvester undergoes a shake, a tilt, or a combination of the two, the ball hits one PC, inducing an impact-based frequency-up conversion. Prototypes of the harvesters have been designed, fabricated, fastened to the wrist of a person by means of a wristband and watchband, and experimentally tested for different motion levels. The PCs of the harvesters have been fed to passive diode-based voltage-doubler rectifiers connected in parallel to a storage capacitor, Cs = 220 nF. By employing the mono-axial harvester, after 8.5 s of consecutive impacts induced by rotations of the wrist, a voltage vcs(t) of 40.2 V across the capacitor was obtained, which corresponded to a stored energy of 178 µJ. By employing the bi-axial harvester, the peak instantaneous power provided by the PCs to an optimal resistive load was 1.58 mW, with an average power of 9.65 µW over 0.7 s. The proposed harvesters are suitable to scavenge electrical energy from low-frequency nonperiodical mechanical movements, such as human motion.

Experimental Characterization of Optimized Piezoelectric Energy Harvesters for Wearable Sensor Networks.

The development of wearable devices and remote sensor networks progressively relies on their increased power autonomy, which can be further expanded by replacing conventional power sources, characterized by limited lifetimes, with energy harvesting systems. Due to its pervasiveness, kinetic energy is considered as one of the most promising energy forms, especially when combined with the simple and scalable piezoelectric approach. The integration of piezoelectric energy harvesters, generally in the form of bimorph cantilevers, with wearable and remote sensors, highlighted a drawback of such a configuration, i.e., their narrow operating bandwidth. In order to overcome this disadvantage while maximizing power outputs, optimized cantilever geometries, developed using the design of experiments approach, are analysed and combined in this work with frequency up-conversion excitation that allows converting random kinetic ambient motion into a periodical excitation of the harvester. The developed optimised designs, all with the same harvesters' footprint area of 23 × 15 mm, are thoroughly analysed via coupled harmonic and transient numerical analyses, along with the mostly neglected strength analyses. The models are validated experimentally via innovative experimental setups. The thus-proposed ϕ = 50 mm watch-like prototype allows, by using a rotating flywheel, the collection of low-frequency (ca. 1 to 3 Hz) human kinetic energy, and the periodic excitation of the optimized harvesters that, oscillating at their eigenfrequencies (~325 to ~930 Hz), display specific power outputs improved by up to 5.5 times, when compared to a conventional rectangular form, with maximal power outputs of up to >130 mW and average power outputs of up to >3 mW. These power levels should amply satisfy the requirements of factual wearable medical systems, while providing also an adaptability to accommodate several diverse sensors. All of this creates the preconditions for the development of novel autonomous wearable devices aimed not only at sensor networks for remote patient monitoring and telemedicine, but, potentially, also for IoT and structural health monitoring.

Dynamic Modeling and Experimental Validation of an Impact-Driven Piezoelectric Energy Harvester in Magnetic Field.

In this study, an impact-driven piezoelectric energy harvester (PEH) in magnetic field is presented. The PEH consists of a piezoelectric cantilever beam and plural magnets. At its initial status, the beam tip magnet is attracted by a second magnet. The second magnet is moved away by hand and then the beam tip magnet moves to a third magnet by the guidance of the magnetic fields. The impact occurs when the beam motion is stopped by the third magnet. The impact between magnets produces an impact energy and causes a transient beam vibration. The electric energy is generated by the piezoelectric effect. Based on the energy principle, a multi-DOF (multi-degree of freedom) mathematical model was developed to calculate the displacements, velocities, and voltage outputs of the PEH. A prototype of the PEH was fabricated. The voltages outputs of the beam were monitored by an oscilloscope. The maximum generated energy was about 0.4045 mJ for a single impact. A comparison between numerical and experimental results was presented in detail. It showed that the predictions based on the model agree with the experimental measurements. The PEH was connected to a diode bridge rectifier and a storage capacitor. The charges generated by the piezoelectric beam were stored in the capacitor by ten impacts. The experiments showed that the energy stored in the capacitor can light up the LED.

A Piezoelectric Wave-Energy Converter Equipped with a Geared-Linkage-Based Frequency Up-Conversion Mechanism.

In this paper, a piezoelectric wave-energy converter (PWEC), consisting of a buoy, a frequency up-conversion mechanism, and a piezoelectric power-generator component, is developed. The frequency up-conversion mechanism consists of a gear train and geared-linkage mechanism, which converted lower frequencies of wave motion into higher frequencies of mechanical motion. The slider had a six-period displacement compared to the wave motion and was used to excite the piezoelectric power-generation component. Therefore, the operating frequency of the piezoelectric power-generation component was six times the frequency of the wave motion. The developed, flexible piezoelectric composite films of the generator component were used to generate electrical voltage. The piezoelectric film was composed of a copper/nickel foil as the substrate, lead-zirconium-titanium (PZT) material as the piezoelectric layer, and silver material as an upper-electrode layer. The sol-gel process was used to fabricate the PZT layer. The developed PWEC was tested in the wave flume at the Tainan Hydraulics Laboratory, Taiwan (THL). The maximum height and the minimum period were set to 100 mm and 1 s, respectively. The maximum voltage of the measured value was 2.8 V. The root-mean-square (RMS) voltage was 824 mV, which was measured through connection to an external 495 kΩ resistive load. The average electric power was 1.37 µW.

Nd3+ -Yb3+ /Nd3+ -Yb3+ -Li+ co-doped Gd2 O3 phosphors for up and down conversion luminescence.

Frequency up-conversion (UC) emission from the Nd3+ -Yb3+ /Nd3+ -Yb3+ -Li+ co-doped gadolinium oxide (Gd2 O3 ) phosphors prepared by the solution combustion technique in the visible range have been studied by using 980 nm near infrared (NIR) laser diode excitation. The crystalline structure and formation of the cubic phase has been confirmed with the help of X-ray diffraction (XRD) studies. XRD peak shifts have been found towards the lower diffraction angle side in the case of the Nd3+ -Yb3+ -Li+ co-doped phosphors. Surface morphology and particle size information have been observed by using field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM) analysis. Down-conversion emission study under 351 nm excitation in the visible region for the Nd3+ -Yb3+ /Nd3+ -Yb3+ -Li+ co-doped phosphors has been performed. The UC emission bands lying in the green and red region arising from the Nd3+ ions have been enhanced by ~260 times, ~113 times due to incorporation of Li+ ions in the Nd3+ -Yb3+ co-doped phosphors. Photometric characterization has been done for the Nd3+ -Yb3+ /Nd3+ -Yb3+ -Li+ co-doped phosphors. The present study suggests the capability of the synthesized phosphors in near-infrared (NIR) to visible upconverter and luminescent device applications.

Vibro-Shock Dynamics Analysis of a Tandem Low Frequency Resonator-High Frequency Piezoelectric Energy Harvester.

Frequency up-conversion is a promising technique for energy harvesting in low frequency environments. In this approach, abundantly available environmental motion energy is absorbed by a Low Frequency Resonator (LFR) which transfers it to a high frequency Piezoelectric Vibration Energy Harvester (PVEH) via impact or magnetic coupling. As a result, a decaying alternating output signal is produced, that can later be collected using a battery or be transferred directly to the electric load. The paper reports an impact-coupled frequency up-converting tandem setup with different LFR to PVEH natural frequency ratios and varying contact point location along the length of the harvester. RMS power output of different frequency up-converting tandems with optimal resistive values was found from the transient analysis revealing a strong relation between power output and LFR-PVEH natural frequency ratio as well as impact point location. Simulations revealed that higher power output is obtained from a higher natural frequency ratio between LFR and PVEH, an increase of power output by one order of magnitude for a doubled natural frequency ratio and up to 150% difference in power output from different impact point locations. The theoretical results were experimentally verified.

Biothiols-activated near-infrared frequency up-conversion luminescence probe for early evaluation of drug-induced hepatotoxicity.

A novel biothiols-sensitive near-infrared (NIR) fluorescent probe RhDN based on a rhodamine skeleton was developed for early detection of drug-induced hepatotoxicity in living mice. RhDN can be used not only as a conventional large stokes shift fluorescent (FL) probe, but also as a kind of anti-Stokes frequency upconversion luminescence (FUCL) molecular probe, which represents a long wavelength excitation (808 nm) to short wavelength emission (760 nm), and response to Cys/Hcy/GSH with high sensitivity. Compared with traditional FL methods, the FUCL method exhibited a lower detection limit of Cys, Hcy, and GSH in 75.1 nM, 101.8 nM, and 84.9 nM, respectively. We exemplify RhDN for tracking endogenously biothiols distribution in living cells and further realize real-time in vivo bioimaging of biothiols activity in mice with dual-mode luminescence system. Moreover, RhDN has been successfully applied to visualize the detection of drug-induced hepatotoxicity in living mice. Overall, this report presents a unique approach to the development of large stokes shift NIR FUCL molecular probes for in vitro and in vivo biothiols biosensing.

Modeling and Experimental Study of Vibration Energy Harvester with Triple-Frequency-Up Voltage Output by Vibration Mode Switching.

Conventional wireless sensors rely on chemical batteries. Replacing or charging their batteries is tedious and costly in some situations. As usable kinetic energy exists in the environment, harvesting vibration energy and converting it into electrical energy has become a hotspot. However, the power output capability of a conventional piezoelectric energy harvester (PEH) is limited by its low operational frequency. This paper presents a new mechanism for achieving continuous triple-frequency-up voltage output in a PEH. The proposed system consists of a slender piezoelectric cantilever with two short cantilever-based stoppers. The piezoelectric cantilever undergoes a pure bending mode without contacting the stoppers. In addition, the beam switches into a new vibration mode by contacting the stoppers. The vibration modes switching yields reverses the signs of voltage outputs, inducing triple-frequency-up voltage output. Analytical and experimental investigations are presented, and it is shown that a significant triple-frequency up-conversion of the voltage output can be obtained over a wide frequency range. A peak power output of 3.03 mW was obtained. The proposed energy harvester can support a wireless sensor node.

A Frequency Up-Conversion Piezoelectric Energy Harvester Shunted to a Synchronous Electric Charge Extraction Circuit.

A frequency up-conversion piezoelectric energy harvester (FUC-PEH) consists of a force amplifier, a piezoelectric stack, a low-frequency oscillator (LFO), and a stop limiter. The force amplifier generates the amplification of stress on the piezoelectric stack. The LFO, comprising a spring and a mass block, impacts the stop limiter during vibration to induce high-frequency oscillations within the piezoelectric stack. In this paper, we represent and simplify the FUC-PEH as a lumped-parameter model based on piezoelectric material constitutive equations and structural dynamic theories. Using the electromechanical analogy, we developed an equivalent circuit model (ECM) of the FUC-PEH. A parametric study was performed to investigate the impact of system parameters, such as spring stiffness and concentrated mass, on the FUC-PEH performance. The collision-induced amplitude truncation (AT) effect enlarges the operation bandwidth. ECM simulations show that low-frequency input excitation is converted into a high-frequency output response, enhancing the energy conversion efficiency. Furthermore, we aimed to improve the FUC-PEH's performance using a synchronous electric charge extraction (SECE) circuit. Using the ECM approach, we established a system-level model that considers the electromechanical coupling behavior. The simulation results provide insights into the performance of FUC harvesters with SECE circuits and offer valuable design guidance.

A Blade-Type Triboelectric-Electromagnetic Hybrid Generator with Double Frequency Up-Conversion Mechanism for Harvesting Breeze Wind Energy.

Triboelectric nanogenerators (TENGs) have garnered substantial attention in breeze wind energy harvesting. However, how to improve the output performance and reduce friction and wear remain challenging. To this end, a blade-type triboelectric-electromagnetic hybrid generator (BT-TEHG) with a double frequency up-conversion (DFUC) mechanism is proposed. The DFUC mechanism enables the TENG to output a high-frequency response that is 15.9 to 300 times higher than the excitation frequency of 10 to 200 rpm. Coupled with the collisions between tribomaterials, a higher surface charge density and better generating performance are achieved. The magnetization direction and dimensional parameters of the BT-TEHG were optimized, and its generating characteristics under varying rotational speeds and electrical boundary conditions were studied. At wind speeds of 2.2 and 10 m/s, the BT-TEHG can generate, respectively, power of 1.30 and 19.01 mW. Further experimentation demonstrates its capacity to charge capacitors, light up light emitting diodes (LEDs), and power wireless temperature and humidity sensors. The demonstrations show that the BT-TEHG has great potential applications in self-powered wireless sensor networks (WSNs) for environmental monitoring of intelligent agriculture.

Comparison of Four Electrical Interfacing Circuits in Frequency Up-Conversion Piezoelectric Energy Harvesting.

Efficiently scavenging piezoelectric vibration energy is attracting a lot of interest. One important type is the frequency up-conversion (FUC) energy harvester, in which a low-frequency beam (LFB) impacts a high-frequency beam (HFB). In this paper, four interface circuits, standard energy harvesting (SEH), self-powered synchronous electric charge extraction (SP-SECE), self-powered synchronized switch harvesting on inductor (SP-SSHI) and self-powered optimized SECE (SP-OSECE), are compared while rectifying the generated piezoelectric voltage. The efficiencies of the four circuits are firstly tested at constant displacement and further analyzed. Furthermore, the harvested power under FUC is tested for different electromechanical couplings and different load values. The results show that SP-OSECE performs best in the case of a weak coupling or low-load resistance, for which the maximum power can be 43% higher than that of SEH. As the coupling level increases, SP-SSHI becomes the most efficient circuit with a 31% higher maximum power compared to that of SEH. The reasons for the variations in each circuit with different coupling coefficients are also analyzed.

Three Frequency Up-Converting Piezoelectric Energy Harvesters Caused by Internal Resonance Mechanism: A Narrative Review.

Low frequency mechanical vibrations are ubiquitous in practical environments, and how to efficiently harvest them with piezoelectric materials remains a challenge. Frequency up-conversion strategies-up-converting low frequency vibrations to high frequency self-oscillations-can improve the power density of piezoelectric materials. This paper mainly introduces a kind of frequency which up-converts piezoelectric energy harvesters based on an internal resonance mechanism, compared with the other mechanisms caused by mechanical impact, mechanical plucking, etc.; the internal resonance-based harvesters can up-convert the frequency under a condition of lower excitation level, less energy loss, and less wideband operation bandwidth. Benefits to practical vibrations also exist in these multi-degree-of-freedom nonlinear dynamic systems. Moreover, the value of the frequency up-conversion factor based on the 1:2:6 internal resonance mechanism can reach as much as six so far, which is also a quite a high frequency up-conversion value.

Theoretical and Experimental Investigation of a Rotational Magnetic Couple Piezoelectric Energy Harvester.

With the rapid development of Internet of Things (IoT) and the popularity of wireless sensors, using internal permanent or rechargeable batteries as a power source will face a higher maintenance workload. Therefore, self-powered wireless sensors through environmental energy harvesting are becoming an important development trend. Among the many studies of energy harvesting, the research on rotational energy harvesting still has many shortcomings, such as rarely working effectively under low-frequency rotational motion or working in a narrow frequency band. In this article, a rotational magnetic couple piezoelectric energy harvester is proposed. Under the low-frequency excitation (<10 Hz) condition, the harvester can convert low-frequency rotational into high-frequency vibrational of the piezoelectric beam by frequency up-conversion, effectively increasing the working bandwidth (0.5−16 Hz) and improving the efficiency of low-speed rotational energy harvesting. In addition, when the excitation frequency is too high (>16 Hz), it can solve the condition that the piezoelectric beam cannot respond in time by frequency down-conversion. Therefore, the energy harvester still has a certain degree of energy harvesting ability (18−22 Hz and 29−31 Hz) under high-frequency conditions. Meanwhile, corresponding theoretical analyses and experimental verifications were carried out to investigate the dynamic characteristics of the harvester with different excitation and installation directions. The experimental results illustrate that the proposed energy harvester has a wider working bandwidth benefiting from the frequency up-conversion mechanism and frequency down-conversion mechanism. In addition, the forward beam will have a wider bandwidth than the inverse beam due to the softening effect. In addition, the maximum powers of the forward and inverse beams at 310 rpm (15.5 Hz) are 93.8 µW and 58.5 µW, respectively. The maximum powers of the two beams at 420 rpm (21 Hz) reached 177 µW and 85.2 µW, respectively. The self-powered requirement of micromechanical systems can be achieved. Furthermore, this study provides the theoretical and experimental basis for rotational energy harvesting.

Fully Integrated High-Performance MEMS Energy Harvester for Mechanical and Contactless Magnetic Excitation in Resonance and at Low Frequencies.

Energy harvesting and storage is highly demanded to enhance the lifetime of autonomous systems, such as IoT sensor nodes, avoiding costly and time-consuming battery replacement. However, cost efficient and small-scale energy harvesting systems with reasonable power output are still subjects of current development. In this work, we present a mechanically and magnetically excitable MEMS vibrational piezoelectric energy harvester featuring wafer-level integrated rare-earth micromagnets. The latter enable harvesting of energy efficiently both in resonance and from low-g, low-frequency mechanical energy sources. Under rotational magnetic excitation at frequencies below 50 Hz, RMS power output up to 74.11 µW is demonstrated in frequency up-conversion. Magnetic excitation in resonance results in open-circuit voltages > 9 V and RMS power output up to 139.39 µW. For purely mechanical excitation, the powder-based integration process allows the realization of high-density and thus compact proof masses in the cantilever design. Accordingly, the device achieves 24.75 µW power output under mechanical excitation of 0.75 g at resonance. The ability to load a capacitance of 2.8 µF at 2.5 V within 30 s is demonstrated, facilitating a custom design low-power ASIC.

High Speed Quantum Key Distribution Over Optical Fiber Network System.

The National Institute of Standards and Technology (NIST) has developed a number of complete fiber-based high-speed quantum key distribution (QKD) systems that includes an 850 nm QKD system for a local area network (LAN), a 1310 nm QKD system for a metropolitan area network (MAN), and a 3-node quantum network controlled by a network manager. This paper discusses the key techniques used to implement these systems, which include polarization recovery, noise reduction, frequency up-conversion detection based on a periodically polled lithium nitrate (PPLN) waveguide, custom high-speed data handling boards and quantum network management. Using our quantum network, a QKD secured video surveillance application has been demonstrated. Our intention is to show the feasibility and sophistication of QKD systems based on current technology.