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1.
Food Chem ; 298: 124971, 2019 Nov 15.
Artigo em Inglês | MEDLINE | ID: mdl-31260997

RESUMO

The BRS Violeta grape presents pulp and skin with high content of phenolic compounds (PCs) and intense purplish color. It was used as raw material for the production of juice and dehydrated products using foam mat drying at 60, 70 and 80 °C and freeze drying (control). HLPC-DAD-ESI-MSn allowed the evaluation of the quantitative and qualitative changes of the main PCs (anthocyanins, flavonols and hydroxycinnamic acid derivatives (HCAD)) present in the grapes during the processing. The use of the steam extraction method to obtain grape juice allowed a greater extraction of flavonols and, mainly derivatives of hydroxycinnamic acids, when compared with anthocyanins. Drying at 70 °C was the most suitable for the preservation of the PCs and, at the same time, for the reduction of the processing time. The powdered products presented considerable concentrations of total PCs (3-5 mg/g) and antioxidant activity (32-79 (DPPH) or 17-27 (FRAP) mg/g).


Assuntos
Antioxidantes/análise , Indústria de Processamento de Alimentos/métodos , Sucos de Frutas e Vegetais , Fenóis/análise , Vitis/química , Antocianinas/análise , Cromatografia Líquida de Alta Pressão , Cor , Ácidos Cumáricos/análise , Flavonóis/análise , Liofilização , Sucos de Frutas e Vegetais/análise , Pós , Espectrometria de Massas por Ionização por Electrospray , Temperatura
2.
Int J Biol Macromol ; 117: 665-672, 2018 Oct 01.
Artigo em Inglês | MEDLINE | ID: mdl-29857107

RESUMO

This study investigated the potential of guar gum and a double emulsion to increase the thermal stability of anthocyanins. The effect of different guar gum concentrations (0%, 0.25%, 0.50%, 0.75%, 1%, 1.25%, 1.5% and 1.75%) was evaluated in relation to color stability, concentration of anthocyanins and antioxidant capacity under storage for 10 days at 40 °C in the presence of light. The addition of guar gum (0.75-1.75%) significantly increased the color stability and bathochromic displacement of the samples, suggesting the occurrence of a co-pigmentation process. The total anthocyanin content was to 41% after storage in treatments without guar gum, but when using 1.25% guar gum the final concentration was 70% and there was a 2.4 fold increase in the half-life time of anthocyanins. A significant effect of guar gum addition on the antioxidant capacity of the samples was observed. In the second step, the anthocyanins were added together with 1.25% guar gum in the internal aqueous phase of the double emulsion and stored for 10 days at 40 °C in the presence of light. The double emulsion presented high encapsulation efficiency (90.6%) and high kinetic stability under the conditions evaluated, in addition to protecting anthocyanin molecules against degradation.


Assuntos
Antocianinas/química , Antioxidantes/farmacologia , Galactanos/farmacologia , Mananas/farmacologia , Gomas Vegetais/farmacologia , Estabilidade Proteica/efeitos dos fármacos , Emulsões/química , Concentração de Íons de Hidrogênio , Cinética , Pigmentação/efeitos dos fármacos , Temperatura , Água/química
3.
Int J Biol Macromol ; 113: 395-402, 2018 Jul 01.
Artigo em Inglês | MEDLINE | ID: mdl-29499264

RESUMO

A central composite design was used to determine effects of pH (1.16-2.84), extraction temperature (63-97°C) and time (35-85min) on the yield, degree of degree of esterification (DE) and viscosity of pectins extracted. For pectin extraction, the previously sanitized mango shells were dried and crushed to obtain the flour that was treated with an ethanol solution obtaining the alcohol insoluble residue (AIR). Subsequently, the AIR was mixed in ethanol with the extraction solution of hydrochloric acid. Pectin yields ranged from 18.8 to 32.1g/100g of AIR, whereas the degree of esterification (DE) and viscosity values ranged from 62.2 to 86.2% and from 1.58 to 45.85mPa·s, respectively. An inverse correlation was found between extraction yield and viscosity. Relying upon the desirability function, two optimum conditions were determined: 35min30% from the AIR, DE≥70.0% and η≥20.0mPa·s.


Assuntos
Fracionamento Químico/métodos , Mangifera/química , Pectinas/isolamento & purificação , Esterificação , Ácidos Hexurônicos/química , Pectinas/química , Temperatura , Fatores de Tempo , Viscosidade
4.
J Food Sci ; 78(2): E222-8, 2013 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-23317379

RESUMO

UNLABELLED: Peroxidase activity accounts for quality losses in many plant-based foods. The paper provides insight into the inactivation kinetics of peroxidase (POD) in carrot juice treated with pulsed electric fields (PEF). Juice samples were subjected to electric field intensities of 20 to 35 kV/cm for 300 to 2000 µs. Up to 93% of the initial activity was inactivated after treating at 35 kV/cm for 1500 µs. POD activity inactivation correlated well with the increase in energy density input. A first-order fractional conversion model best fitted the experimental results. Other kinetic approaches such as the Fermi's model can be used to estimate residual POD activity values in treated juices as a function of electric field strength. PRACTICAL APPLICATION: Pulsed electric fields (PEF) are a processing technology that can be used for the pasteurization of liquid food products. Peroxidase activity inhibition is required in carrot juices to prevent undesirable quality losses, such as discoloration, flavor changes, and loss of nutrients. The most significant processing parameters ruling POD inactivation in PEF-treated carrot juice are identified and mathematical modeling of experimental data is conducted.


Assuntos
Bebidas/análise , Daucus carota/enzimologia , Manipulação de Alimentos/métodos , Peroxidase/metabolismo , Eletricidade , Cinética , Modelos Teóricos , Dinâmica não Linear , Pasteurização , Peroxidase/antagonistas & inibidores
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