Deep-Ultraviolet Transparent Electrode Design for High-Performance and Self-Powered Perovskite Photodetector.

In this study, a highly crystalline and transparent indium-tin-oxide (ITO) thin film was prepared on a quartz substrate via RF sputtering to fabricate an efficient bottom-to-top illuminated electrode for an ultraviolet C (UVC) photodetector. Accordingly, the 26.6 nm thick ITO thin film, which was deposited using the sputtering method followed by post-annealing treatment, exhibited good transparency to deep-UV spectra (67% at a wavelength of 254 nm), along with high electrical conductivity (11.3 S/cm). Under 254 nm UVC illumination, the lead-halide-perovskite-based photodetector developed on the prepared ITO electrode in a vertical structure exhibited an excellent on/off ratio of 1.05 × 104, a superb responsivity of 250.98 mA/W, and a high specific detectivity of 4.71 × 1012 Jones without external energy consumption. This study indicates that post-annealed ITO ultrathin films can be used as electrodes that satisfy both the electrical conductivity and deep-UV transparency requirements for high-performance bottom-illuminated optoelectronic devices, particularly for use in UVC photodetectors.

Toward Industrial Production of a High-Performance Self-Powered Ultraviolet Photodetector Using Nanoporous Al-Doped ZnO Thin Films.

Al-doped ZnO (AZO) thin films are effective n-type semiconductors for ultraviolet (UV) detection because of their low cost, high electron mobility, and high sensitivity to UV light, especially in the UVA spectrum. However, a reasonable compromise between performance (such as sensitivity, detectivity, and response time) and fabrication ease remains an obstacle to the practicability of AZO-based UV photodetectors. To address this issue, we propose an efficient strategy to achieve a large AZO photoactive area for outstanding performance, along with a facile sol-gel method. Consequently, the device exhibits a superb on/off ratio of >104, a high detectivity of 1.85 × 1012 Jones, and a fast response speed under 365 nm UVA illumination without external energy consumption. Hence, this study suggests a self-powered and high-performance nanoporous AZO-based UVA detector with an environmentally friendly scalable process that satisfies industrial production requirements for numerous practical UV-detection applications.

Recent Advances of Doped SnO2 as Electron Transport Layer for High-Performance Perovskite Solar Cells.

Perovskite solar cells (PSCs) have garnered considerable attention over the past decade owing to their low cost and proven high power conversion efficiency of over 25%. In the planar heterojunction PSC structure, tin oxide was utilized as a substitute material for the TiO2 electron transport layer (ETL) owing to its similar physical properties and high mobility, which is suitable for electron mining. Nevertheless, the defects and morphology significantly changed the performance of SnO2 according to the different deposition techniques, resulting in the poor performance of PSCs. In this review, we provide a comprehensive insight into the factors that specifically influence the ETL in PSC. The properties of the SnO2 materials are briefly introduced. In particular, the general operating principles, as well as the suitability level of doping in SnO2, are elucidated along with the details of the obtained results. Subsequently, the potential for doping is evaluated from the obtained results to achieve better results in PSCs. This review aims to provide a systematic and comprehensive understanding of the effects of different types of doping on the performance of ETL SnO2 and potentially instigate further development of PSCs with an extension to SnO2-based PSCs.

Metal Electrode-Free Halide Perovskite-Based Flexible Ultraviolet-C Photodetector with Large Area.

Ultraviolet-C (UVC) photodetector has appealed to a numerous number of research owing to its manifold applications in wireless communication, flame monitoring, and medicine. However, in addition to superior performance and high stability of recent studies, scalability and production cost are important factors for commercialization and practical implementation. In this study, a halide perovskite-based UVC photodetector was fabricated using spin-coating process and low-temperature annealing. Corning® Willow® Glass was selected as the substrate for the bottom-illuminated device due to its flexibility and exceptional optical transmission (approximately 60%) in the deep-UV region. The device had a vertical structure with a large active area (1 cm2) owing to the judicious utilization of electrodes. Under bent state with a curvature radius of 25 mm, the as-fabricated device exhibited high response and repeatability with an on/off ratio of 9.57 × 103, a fast response speed of 45/46 ms (rise/fall times) at zero bias under the illumination of a 254-nm UV lamp. The results are based on a flexible and lightweight photodetector without the utilization of notable metal electrodes.

Self-Powered UVC Photodetector Based on Europium Metal-Organic Framework for Facile Monitoring Invisible Fire.

The effective use of a europium metal-organic framework (Eu-MOF) as a photoabsorber material has been reported. Using the advantages of Eu-MOFs including simple preparation, wide bandgap structure, and stability in the environment, a self-powered and high UVC-selectivity detector based on Eu-MOF nanoparticles was prepared with a simple device geometry. The as-fabricated photodetector was highly sensitive to 254 nm UV illumination without an external power supply. Accordingly, it exhibited a high UVC-to-UVA rejection ratio (I254/I365 ≈ 40) and UVC-to-solar rejection ratio (I254/Isolar light ≈ 34), a fast response time of 98/122 ms, a comparable on/off photocurrent ratio (107.33), and superior stability. The self-powered Eu-MOF photodetector can detect and monitor UV emission from an invisible fire in an early state at room temperature, suggesting practical use as a potential optoelectronic device.

Recent advances in self-powered and flexible UVC photodetectors.

Ultraviolet-C (UVC) radiation is employed in various applications, including irreplaceable applications in military and civil fields, such as missile guidance, flame detection, partial discharge detection, disinfection, and wireless communication. Although most modern electronics are based on Si, UVC detection technology remains a unique exception because the short wavelength of UV radiation makes efficient detection with Si difficult. In this review, recent challenges in obtaining ideal UVC photodetectors with various materials and various forms are introduced. An ideal photodetector must satisfy the following requirements: high sensitivity, fast response speed, high on/off photocurrent ratio, good regional selectivity, outstanding reproducibility, and superior thermal and photo stabilities. UVC detection is still in its infancy compared to the detection of UVA as well as other photon spectra, and recent research has focused on different key components, including the configuration, material, and substrate, to acquire battery-free, super-sensitive, ultra-stable, ultra-small, and portable UVC photodetectors. We introduce and discuss the strategies for fabricating self-powered UVC photodetectors on flexible substrates in terms of the structure, material, and direction of incoming radiation. We also explain the physical mechanisms of self-powered devices with various architectures. Finally, we present a brief outlook that discusses the challenges and future strategies for deep-UVC photodetectors.

A systematic comparison of the effect of topically applied anthraquinone aglycones to relieve psoriasiform lesion: The evaluation of percutaneous absorption and anti-inflammatory potency.

The anthraquinones derived from rhubarb are reported to have anti-inflammatory activity. The present study aimed to assess the topical application of rhubarb anthraquinone aglycones for psoriasis treatment. The antipsoriatic effect of five anthraquinones, including aloe-emodin, rhein, emodin, physcion, and chrysophanol, was compared to elucidate a structure-permeation relationship. Molecular modeling was employed to determine the physicochemical properties. Both macrophages (differentiated THP-1) and keratinocytes (HaCaT) were used to examine the anti-inflammatory activity in the cell-based study. The in vitro pig skin absorption showed that chrysophanol was the compound with the highest cutaneous accumulation. Topically applied rhein was detected to be largely delivered to the receptor compartment. The absorption of rhein was increased by 5-fold in the barrier-deficient skin as compared to intact skin. By stimulating macrophages with imiquimod (IMQ) to model the inflammation in psoriasis, it was found that the anthraquinones significantly reduced IL-6, IL-23, and TNF. The cytokine inhibition level was comparable for the five compounds. The anthraquinones suppressed cytokines by inhibiting the activation of MAPK and NF-κB signaling. The anthraquinones also downregulated IL-6, IL-8, and IL-24 in the inflammatory keratinocytes stimulated with TNF. Rhein and chrysophanol were comparable to curtail the STAT3 phosphorylation in keratinocytes induced by the conditioned medium of stimulated macrophages. The IMQ-induced psoriasiform mouse model demonstrated the improvement of scaling, erythema, and epidermal hyperplasia by topically applied rhein or chrysophanol. The epidermal acanthosis evoked by IMQ was reduced with rhein and chrysophanol by 3-fold. The histological profiles exhibit that both anthraquinone compounds diminished the number of macrophages and neutrophils in the lesional skin, skin-draining lymph node, and spleen. Rhein and chrysophanol showed multifunctional inhibition, by regulating several targets for alleviating psoriasiform inflammation.

Practical Demonstration of Deep-Ultraviolet Detection with Wearable and Self-Powered Halide Perovskite-Based Photodetector.

Flexible and self-powered photodetectors (PDs) have become one of the most popular topics, attracting researchers in the field of optoelectronic applications. In this study, for the first time, we demonstrate partial discharge detection in a practical environment with a prepared flexible device. Poly(vinylidene fluoride) (PVDF) is utilized as a highly transparent material in the UVC region, to create a flexible substrate with the antihumidity property. A detector that uses a mixed-halide perovskite (FAPbI3)1-x(MAPbBr3)x as the photoactive material is constructed in a vertical structure on the as-prepared hydrophobic PVDF substrate. The fabricated device exhibits good performance with a fast response speed (trise = 82 ms, tfall = 64 ms) and a high detectivity of 7.21 × 1010 Jones at zero bias under 254 nm UV illumination, along with superior mechanical flexibility at various bending angles. Additionally, the air-exposure stability and reproducibility of the as-prepared device exhibit almost the original performance after 6 weeks of storage. For practical applications, we demonstrate a facile and sensitive detection for UVC leakage from a germicidal lamp and simulated a partial discharge system using our PD without energy consumption. These results indicate that this new approach may be useful and convenient for the detection of the partial discharge as well as for several practical applications.

Particle Size Effect of Lanthanum-Modified Bismuth Titanate Ceramics on Ferroelectric Effect for Energy Harvesting.

Piezoelectric nanogenerators (PNGs) have been studied as renewable energy sources. PNGs consisting of organic piezoelectric materials such as poly(vinylidene fluoride) (PVDF) containing oxide complex powder have attracted much attention for their stretchable and high-performance energy conversion. In this study, we prepared a PNG combined with PVDF and lanthanum-modified bismuth titanate (Bi4-XLaXTi3O12, BLT) ceramics as representative ferroelectric materials. The inserted BLT powder was treated by high-speed ball milling and its particle size reduced to the nanoscale. We also investigated the effect of particle size on the energy-harvesting performance of PNG without polling. As a result, nano-sized powder has a much larger surface area than micro-sized powder and is uniformly distributed inside the PNG. Moreover, nano-sized powder-mixed PNG generated higher power energy (> 4 times) than the PNG inserted micro-sized powder.

Synthesis of Cobalt-Doped TiO2 Based on Metal-Organic Frameworks as an Effective Electron Transport Material in Perovskite Solar Cells.

In this study, Co-doped TiO2 was prepared successfully using a solvothermal method with trimesic acid (H3BTC) as an organic framework to form the Co-doped Ti metal-organic framework (Co-doped Ti-MOF). By thermally decomposing the Co-doped Ti-MOF in air, the framework template was removed, and porous Co-doped TiO2 was obtained. The crystal structure of the material was analyzed using X-ray diffraction. The morphology was examined using scanning electron microscopy (SEM) and focused ion beam SEM. The large specific surface area was determined to be 135.95 m2 g-1 using Brunauer-Emmett-Teller theory. Fourier transform infrared spectroscopy verified the presence of Ti-O-Ti and Co-O vibrations in the as-prepared sample. Furthermore, the results of UV-vis spectroscopy showed that doping with Co remarkably improved the absorption ability of Ti-MOF toward the visible-light region with a band gap energy of 2.38 eV (λ = 502 nm). Steady-state photoluminescence and electrochemical impedance spectroscopy were conducted to illustrate the improvement of electron transfer in the doped material further. The optimum power conversion efficiency of solar cells using 1 wt % Co-doped TiO2 as an electron transport layer was found to be 15.75%, while that of solar cells using commercial dyesol TiO2 is only 14.42%.