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1.
Waste Manag ; 164: 84-93, 2023 Jun 01.
Artigo em Inglês | MEDLINE | ID: mdl-37037100

RESUMO

Waste management policies aim to divert waste from lower positions on the waste hierarchy such as landfill and incineration to higher positions in the hierarchy such as energy recovery and recycling. However, empirical evaluations of such policies are scarce. This study highlighted the effect of waste management policies on the amount of waste treated with landfill, incineration, energy recovery and recycling by analysing a panel dataset consisting of 14 European countries and the period 1996 to 2018. Findings from a seemingly unrelated regression model suggest that the landfill ban is associated with a decrease in landfill waste, but an increase in incineration, energy recovery and recycling waste. The landfill tax is also correlated with an increase in energy recovery waste but, in contrast, it is associated with a reduction in incineration and recycling waste. Meanwhile, the deposit refund scheme is associated with a decrease in the amount of landfill waste. Concerning the effects on total waste generated, regression results from a fixed effects model indicate that the landfill tax and the deposit refund scheme are both correlated with a reduction in the amount of waste generated. These findings contribute to the scarce academic literature evaluating waste management policies and may better inform policy makers on their longer-term implications.


Assuntos
Eliminação de Resíduos , Gerenciamento de Resíduos , Gerenciamento de Resíduos/métodos , Instalações de Eliminação de Resíduos , Incineração/métodos , Europa (Continente) , Reciclagem/métodos , Resíduos Sólidos/análise
2.
Meat Sci ; 183: 108616, 2022 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-34481232

RESUMO

This cross-country study investigates the potential to improve pig welfare by exploiting consumer demand, domestically and in export markets, for welfare pork produced in indoor production systems. The analysis is based on questionnaire data collected in 2019 focusing on demand for Danish welfare pork both in Denmark and in two nearby export markets, Sweden and Germany. To reduce hypothetical bias, a willingness-to-pay indicator is combined with an indicator of positive interest in buying a fictive Danish welfare labelled pork. We find that the market potential is relatively weak. Our findings indicate that there is some, albeit limited, potential in Denmark and Germany while demand is practically non-existing in Sweden, probably because the pig welfare guaranteed by Swedish legislation is similar to what is provided by the fictive welfare label employed in the study. Hence, consumer demand alone cannot secure enhanced pig welfare. Moreover, we found national differences in the characteristics of consumers who are interested in Danish welfare pork.


Assuntos
Bem-Estar do Animal , Comportamento do Consumidor/estatística & dados numéricos , Carne de Porco/normas , Adulto , Animais , Comportamento do Consumidor/economia , Estudos Transversais , Dinamarca , Feminino , Alemanha , Humanos , Masculino , Pessoa de Meia-Idade , Carne de Porco/economia , Inquéritos e Questionários , Suécia , Suínos
3.
Soc Sci Med ; 287: 114388, 2021 10.
Artigo em Inglês | MEDLINE | ID: mdl-34520938

RESUMO

Taxes and subsidies on foods and nutrients have the potential to promote healthier diets and thereby reduce mortality. In this study, we examine the effects of such policy instruments on Swedish public health. Specifically, we estimate the effects of food and nutrient taxes and subsidies on mortality averted and postponed in Sweden, using both demand system estimations and simulation models. We evaluate different Value Added Tax (VAT) reforms. The VAT is raised on food products that are particularly rich in saturated fat or salt and lowered on fruit and vegetables. Our models predict that an increase in the current VAT of 12% on food, to 25% VAT on products rich in saturated fat plus a 0% VAT on fruits and vegetables would result in almost 1100 deaths (95% CI: -832; -1363) averted or postponed in a year in Sweden, while the combination of a 34.4% VAT on products rich in saturated fat and a -10.4% VAT (i.e. a subsidy) on fruits and vegetables would result in almost 2100 (95% CI: -1572; -2311) deaths averted or postponed corresponding to a 4.8% reduction in diet-related annual death. Most of the deaths averted or delayed from this reform would be deaths from coronary heart disease (-1,148, 95% CI: -728; -1586), followed by stroke -641 (95% CI: -408; -887) and diet-related cancer deaths (-288, 95% CI: -11; -435). We find that health-related food taxes and subsidies improve dietary habits as well as reduce the mortality of the Swedish population. However, the effect of these reforms on different socioeconomic classes and which reforms provide the best value for money, i.e., cost-effectiveness of these reforms needs to be established first before implementation.


Assuntos
Alimentos , Impostos , Dieta , Frutas , Humanos , Nutrientes , Verduras
4.
Public Health Nutr ; 24(12): 3956-3965, 2021 08.
Artigo em Inglês | MEDLINE | ID: mdl-33977893

RESUMO

OBJECTIVE: The objective is to analyse Danish consumers' attitudes to buying food with reduced salt content. DESIGN: The study is based on a comprehensive store intervention that included 114 stores belonging to the same supermarket chain. Three different salt claims were tested for 8 weeks on six test products within the categories bread, cornflakes and frozen pizzas. Scanner data were supplemented with 134 brief interviews with consumers in nine selected stores. SETTING: Stores spread across Denmark. PARTICIPANTS: Consumers who buy food in the stores. RESULTS: Statistical regression analyses of the scanner data indicated that none of the three claims significantly affected demand for any of the test products. The interviews confirmed that many consumers were more focused on other elements of the official dietary advice than reduced salt consumption, such as eating plenty of vegetables, choosing products with whole grains and reducing their intake of sugar and fat. CONCLUSIONS: Overall, both the scanner data and the interviews pointed in the same direction, towards the conclusion that salt content is often a secondary factor when Danish consumers make dietary choices.


Assuntos
Comportamento do Consumidor , Supermercados , Pão , Dinamarca , Preferências Alimentares , Humanos
5.
Animals (Basel) ; 11(2)2021 Jan 28.
Artigo em Inglês | MEDLINE | ID: mdl-33525675

RESUMO

BACKGROUND: The relationship between animal ethics orientations and consumer demand for meat with high standards of animal welfare, and the way this relationship plays out in different countries, is not well understood. Using pork as a case study, this comparative study aims to identify the animal ethics orientations that drive purchases of welfare meat in Denmark, Germany, and Sweden. METHODS: Cross-sectional questionnaire data from representative samples of approximately 1600 consumers in each country were collected. A segmentation of pork consumers (using latent profile analysis) was carried out. RESULTS: In all three countries, two subgroups were concerned about farm animal welfare: the first subgroup was driven by animal rights values; the second subgroup by animal protection values, where the main principle was that "it is all right to use animals as long as they are treated well". Other consumer groups are less concerned about farm animal welfare and display little or no preference for welfare pork. CONCLUSIONS: In all three countries, dual demand for welfare pork exists. The findings of this study can be used, among others, to understand the marketability of enhanced welfare animal products and the potential for market-driven animal welfare improvements.

6.
PLoS One ; 15(4): e0231105, 2020.
Artigo em Inglês | MEDLINE | ID: mdl-32294098

RESUMO

It is well understood that adding to the population increases CO2 emissions. At the same time, having children is a transformative experience, such that it might profoundly change adult (i.e., parents') preferences and consumption. How it might change is, however, unknown. Depending on if becoming a parent makes a person "greener" or "browner," parents may either balance or exacerbate the added CO2 emissions from their children. Parents might think more about the future, compared to childless adults, including risks posed to their children from environmental events like climate change. But parenthood also adds needs and more intensive competition on your scarce time. Carbon-intensive goods can add convenience and help save time, e.g., driving may facilitate being in more places in one day, compared to public transportation or biking. Pre-prepared food that contain red meat may save time and satisfy more household preferences, relative to vegetarian food. We provide the first rigorous test of whether parents are greener or browner than other adults. We create a unique dataset by combining detailed micro data on household expenditures of all expenditure groups particularly important for CO2 emissions (transportation, food, and heating/electricity) with CO2 emissions, and compare emissions from Swedish adults with and without children. We find that parents emit more CO2 than childless adults. Only a small fraction of adults permanently choose not to have children, which means any meaningful self-selection into parenthood based on green preferences is unlikely. Our findings suggest that having children might increase CO2 emissions both by adding to the population and by increasing CO2 emissions from those choosing to have children.


Assuntos
Dióxido de Carbono/efeitos adversos , Pegada de Carbono/estatística & dados numéricos , Conservação dos Recursos Naturais , Pais/psicologia , Crescimento Demográfico , Adolescente , Adulto , Criança , Pré-Escolar , Conjuntos de Dados como Assunto , Características da Família , Feminino , Humanos , Lactente , Recém-Nascido , Masculino , Pessoa de Meia-Idade , Suécia , Adulto Jovem
7.
Sci Rep ; 10(1): 1610, 2020 01 31.
Artigo em Inglês | MEDLINE | ID: mdl-32005872

RESUMO

Seaweed cultivation is a large industry worldwide, but production in Europe is small compared to production in Asian countries. In the EU, the motivations for seaweed farming may be seen from two perspectives; one being economic growth through biomass production and the other being the provisioning of ecosystem services such as mitigating eutrophication. In this paper, we assess the economic potential of large-scale cultivation of kelp, Saccharina latissima, along the Swedish west coast, including the value of externalities. The findings suggest that seaweed farming has the potential of becoming a profitable industry in Sweden. Furthermore, large-scale seaweed farming can sequester a significant share of annual anthropogenic nitrogen and phosphorus inflows to the basins of the Swedish west coast (8% of N and 60% of P). Concerning the valuation of externalities, positive values generated from sequestration of nitrogen and phosphorus are potentially counteracted by negative values from interference with recreational values. Despite the large N and P uptake, the socioeconomic value of this sequestration is only a minor share of the potential financial value from biomass production. This suggests that e.g. payment schemes for nutrient uptake based on the socioeconomic values generated is not likely to be a tipping point for the industry. Additionally, seaweed cultivation is not a cost-efficient measure in itself to remove nutrients. Policy should thus be oriented towards industry development, as the market potential of the biomass will be the driver that may unlock these bioremediation opportunities.


Assuntos
Alga Marinha/crescimento & desenvolvimento , Aquicultura/métodos , Ásia , Biomassa , Ecossistema , Kelp/crescimento & desenvolvimento , Kelp/metabolismo , Nitrogênio/metabolismo , Nutrientes/metabolismo , Fósforo/metabolismo , Alga Marinha/metabolismo , Fatores Socioeconômicos , Suécia
8.
Nutrients ; 11(6)2019 Jun 25.
Artigo em Inglês | MEDLINE | ID: mdl-31242671

RESUMO

The objective of this study is to estimate the number of deaths attributable to cardiovascular diseases and diet-related cancers that could be prevented or delayed in the Nordic countries, i.e., Sweden, Denmark, Finland, Norway, and Iceland, if adults adhere to the Nordic Nutrition Recommendations (NNR). A sex- and age-group specific epidemiological macro-simulation model was used to estimate the preventable deaths due to the differences between country specific actual intake and recommended intake of changes in food components. Data included in the model are a baseline scenario (actual dietary intake), a counterfactual scenario (recommended intake), and age-and sex-specific mortality for cardiovascular and diet-related cancer diseases, together with the total population risk of a specific year. Monte Carlo analyses with 5000 iterations were performed to produce the 95% uncertainty intervals. The model predicts that Iceland would benefit the most by adhering to the NNR, followed by Finland. In all the Nordic countries, the highest benefit would be achieved by adhering to the fruits and vegetable intakes, except Denmark, where a lower recommended intake of salt would provide the highest benefit. For men, fruits and vegetables could have saved more lives compared to other dietary components for all the Nordic countries, while for women, dietary fiber was the most prominent factor, except in Iceland. The Nordic Council should consider policies for promoting healthy eating according to the needs of each country.


Assuntos
Doenças Cardiovasculares/prevenção & controle , Dieta Saudável , Neoplasias/prevenção & controle , Estado Nutricional , Valor Nutritivo , Comportamento de Redução do Risco , Adolescente , Adulto , Fatores Etários , Idoso , Idoso de 80 Anos ou mais , Doenças Cardiovasculares/mortalidade , Causas de Morte , Criança , Pré-Escolar , Simulação por Computador , Fibras na Dieta , Feminino , Frutas , Humanos , Masculino , Pessoa de Meia-Idade , Método de Monte Carlo , Neoplasias/mortalidade , Fatores de Proteção , Recomendações Nutricionais , Fatores de Risco , Países Escandinavos e Nórdicos/epidemiologia , Fatores Sexuais , Verduras , Adulto Jovem
9.
Artigo em Inglês | MEDLINE | ID: mdl-30870975

RESUMO

The objective is to estimate the number of deaths attributable to cardiovascular diseases and diet-related cancers that could be prevented or delayed in Sweden if adults adhere to the official dietary recommendations. We used an age-group and sex-specific epidemiological macro-simulation model to estimate preventable deaths due to the discrepancies between actual intake and recommended intake of changes in food components. Data included in the model are a baseline scenario (actual dietary intake), a counterfactual scenario (recommended intake) and age- and sex-specific mortality for cardiovascular and diet-related cancer diseases together compared with the total population risk of a specific year. Monte Carlo analyses with 5000 iterations was performed to produce the 95% uncertainty intervals (UI). The model predicts that 6405 (95% UI: 5086⁻7086) deaths could be prevented or delayed if the Swedish population could adhere to official dietary recommendations in a year. More deaths would be saved for men than women. The recommendations for fruits and vegetables could have saved 47% of the deaths, followed by fiber intake (32%). For men, fruits and vegetables could have saved more compared to other dietary components, while for women dietary fiber was the prominent factor. Public health policies should consider ensuring healthy eating practices for the Swedish population.


Assuntos
Doenças Cardiovasculares/mortalidade , Doenças Cardiovasculares/prevenção & controle , Dieta Saudável , Modelos Biológicos , Neoplasias/mortalidade , Neoplasias/prevenção & controle , Adulto , Doenças Cardiovasculares/epidemiologia , Simulação por Computador , Dieta , Fibras na Dieta , Feminino , Frutas , Humanos , Masculino , Pessoa de Meia-Idade , Método de Monte Carlo , Neoplasias/epidemiologia , Fatores de Risco , Fatores Sexuais , Suécia/epidemiologia , Incerteza , Verduras
10.
Ambio ; 47(4): 398-409, 2018 May.
Artigo em Inglês | MEDLINE | ID: mdl-28940171

RESUMO

Efforts are on the way on the Swedish West Coast to develop the capacity for cultivation of marine resources, notably of kelps. Given that this is a region of great natural and national heritage, public opposition to marine developments has been identified as a possible risk factor. This survey thus sought to shed light on awareness levels, perceptions of different types of aquaculture and on reactions to a scenario depicting future aquaculture developments on the West Coast. When asked about their general opinions of aquaculture, respondents tended to be favourable though a majority chose neutral responses. On the whole, respondents were favourable to the depicted scenario. Finally, it was found that the high-awareness group tended to be more supportive than the low or medium-awareness groups, hinting at the benefits of increasing awareness to reduce public aversion and to support a sustainable development of aquaculture on the Swedish West Coast.


Assuntos
Aquicultura , Conservação dos Recursos Naturais , Animais , Biodiversidade , Feminino , Humanos , Masculino , Percepção , Opinião Pública , Suécia
11.
Neuroophthalmology ; 41(5): 241-246, 2017 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-29339957

RESUMO

We previously reported that some healthy individuals show alternating anisocoria. We now describe one such individual who also exhibits a classic nasal cycle (alternating periods of nasal congestion and decongestion). We made measurements of his pupil asymmetry and nasal asymmetry at 21 different time points and found that these variables were always synchronised such that greater nasal airflow was invariably found on the same side as the larger pupil. We hypothesise that a common central oscillator may be responsible for co-modulating the sympathetic outflow to both nasal vessels and iris dilator muscles in some healthy individuals.

12.
Parasit Vectors ; 9: 221, 2016 Apr 19.
Artigo em Inglês | MEDLINE | ID: mdl-27094215

RESUMO

BACKGROUND: The epidemiology of the zoonotic tick-transmitted parasite Babesia spp. and its occurrence in wild reservoir hosts in Sweden is unclear. In European deer, several parasite species, including Babesia capreoli and the zoonotic B. venatorum and B. divergens has been reported previously. The European roe deer, Capreolus capreolus, is an important and common part of the indigenous fauna in Europe, as well as an important host for Ixodes ricinus ticks, the vector of several Babesia spp. in Europe. Here, we aimed to investigate the occurrence of Babesia spp. in roe deer in Sweden. FINDINGS: Roe deer (n = 77) were caught and sampled for blood. Babesia spp. was detected with a PCR assay targeting the 18S rRNA gene. The prevalence of Babesia spp. was 52%, and two species were detected; B. capreoli and B. venatorum in 44 and 7.8% of the individuals, respectively. Infection occurred both in summer and winter. CONCLUSIONS: We showed that roe deer in Sweden, close to the edge of their northern inland distributional range, are infected with Babesia spp. The occurrence of B. venatorum in roe deer imply that it is established in Sweden and the zoonotic implication of this finding should be regarded to a greater extent in future.


Assuntos
Animais Selvagens/parasitologia , Babesia/genética , Babesia/isolamento & purificação , Babesiose/parasitologia , Cervos/parasitologia , Animais , Babesia/classificação , Estações do Ano , Suécia
13.
Appetite ; 89: 103-11, 2015 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-25662697

RESUMO

Food high in energy but low in nutritional value is an important contributor to several serious illnesses, and one type of food that is particularly high in energy but low in nutrition is food consumed away from home. In this paper, we examine the demand and willingness to pay for healthy, Keyhole-labelled meals. A Keyhole-labelled meal is particularly low in energy, fat, sugar and salt, but particularly high in fibre. The results suggest that to get the majority of individuals to choose the healthy option regularly it would be necessary to alter the relative price between healthy and less healthy meals. Generally groups of individuals with a poor nutritional intake require a larger compensation (subsidy) before they choose the healthy alternative. About one third of respondents would choose the healthy option regularly if the prices for a healthy and less healthy meal were the same. In particular groups of individuals who already have a relatively good nutritional intake would select the healthy option. Groups with a generally poor nutritional intake (men and individuals with lower education and lower income) would gain health benefits from a subsidy of Keyhole-labelled meals.


Assuntos
Comportamento de Escolha , Comércio , Dieta/economia , Preferências Alimentares , Comportamentos Relacionados com a Saúde , Refeições , Restaurantes/economia , Adulto , Dieta/normas , Fibras na Dieta , Comportamento Alimentar , Feminino , Humanos , Masculino , Pessoa de Meia-Idade , Estado Nutricional , Valor Nutritivo , Inquéritos e Questionários
14.
J Colloid Interface Sci ; 397: 9-17, 2013 May 01.
Artigo em Inglês | MEDLINE | ID: mdl-23484773

RESUMO

Alkaline sodium silicate solutions with SiO2:Na2O molar ratios in the range 4-10 are known to be colloidally unstable manifested in phase separation or gelation. The mechanistic understanding of this instability is generally poor. To improve this situation the microscopic structure of a series of solutions with ratios in the range 3.3-8.9 has been characterised using small-angle X-ray scattering, Dynamic light scattering, Fourier transformed infrared spectroscopy, and (29)Si Nuclear magnetic resonance spectroscopy to cover the relevant length scales related to silica clusters, aggregates, and particles present. In the starting solution, with ratio 3.3, there are silica present in three fractions. The main part is present as small silica clusters with a radius of 0.7 nm. There are also a significant portion of monomers/small oligomeric silica species as well as a minute amount of larger colloidal silica particles. At a higher SiO2:Na2O ratio, above approximately 4, smaller spherical colloidal particles are formed due to condensation reactions. However, as a result of a too high ionic strength the suspension is not stable and the particles aggregate to fractal structures with a size that depends on ratio and ageing time. At the highest SiO2:Na2O ratio, fractals are not formed because of the lower ionic strength and the smaller colloidal particles are stable in the solution. By carefully adding small amounts of NaCl to the high ratio solution it is possible to induce gelation of the solution confirming the hypothesis that the instability region is due to too high electrolyte concentration for the silica species present under those conditions.

15.
Langmuir ; 28(9): 4080-5, 2012 Mar 06.
Artigo em Inglês | MEDLINE | ID: mdl-22300339

RESUMO

We have investigated the stability and interactions in dispersions of colloidal fumed silica, Aerosil 200, and the ionic liquid 1-butyl-3-methylimidazolium tetraflouroborate (BMImBF(4)) as a function of the Li salt concentration (LiBF(4)). Photon correlation spectroscopy was used to study the aggregation behavior at low silica concentrations, and Raman spectroscopy was used to investigate the interactions in the ionic liquid and with the silica surface. We find that the addition of LiBF(4) increases the stability of the dispersions, with smaller agglomerates of silica particles and higher gelation concentrations in the presence of Li salt. The increased stability with the addition of Li salt is explained by the formation of a more stable solvation layer, where Li ions accumulate on the surface. This leads to an increased interaction between lithium ions and the BF(4)(-) anions in the solvation layer, as seen by Raman spectroscopy. Upon gelation, the Li ions are expelled from the surface because hydrogen bonding between the silica particles are formed. For both neat BMImBF(4) and Li-salt-doped BMImBF(4)/silica dispersions, a weak gel phase was found preceding the formation of a strong gel at slightly higher silica concentrations.

16.
Appetite ; 58(1): 168-79, 2012 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-21983052

RESUMO

The primary objective of this study was to estimate the willingness to pay (WTP) for a new intervention at the workplace: wholesome canteen takeaways (CTA), i.e. a low fat meal with a large amount of vegetables prepared at the workplace canteen that only requires re-heating. The contingent valuation method was used to elicit the WTP. Two surveys were carried out in Denmark; one large-scale Internet based survey and one survey at a workplace that introduced CTA. The results from the large-scale survey suggest that this concept attracts relevant target groups; groups of individuals with a less healthy diet, low physical activity and a high body mass index. For males and individuals with low education, who also constitute relevant target groups, the results suggest no significant difference in WTP between males and females, whereas low educated individuals have a significantly lower WTP than highly educated individuals. However, the workplace study, carried out at a hospital, found that females have a significantly higher WTP for CTA compared with males. In conclusion, the concept appears to attract relevant target groups, although for a given price a smaller fraction of low educated individuals compared to high educated individuals would be willing to buy CTA.


Assuntos
Fast Foods/economia , Serviços de Alimentação , Alimentos Orgânicos/economia , Adolescente , Adulto , Idoso , Atitude Frente a Saúde , Índice de Massa Corporal , Dinamarca , Dieta , Inquéritos sobre Dietas , Feminino , Humanos , Estilo de Vida , Masculino , Pessoa de Meia-Idade , Modelos Teóricos , Atividade Motora , Inquéritos e Questionários , Adulto Jovem
17.
J Colloid Interface Sci ; 356(1): 37-45, 2011 Apr 01.
Artigo em Inglês | MEDLINE | ID: mdl-21272893

RESUMO

In this study two routes for the gelation of water glass have been investigated; the destabilization by a change in pH and by an increase in concentration through evaporation. Both methods produce optically transparent, highly viscous, homogeneous solutions. The structure and dynamics of the solutions along the two routes have been investigated with dynamic light scattering, (29)Si-Nuclear Magnetic Resonance spectroscopy, viscosity measurements and infrared spectroscopy. We find that the two routes are fundamentally different. Increasing the concentration of the sodium silicate system leaves the silica speciation apparently unchanged. Lowering the pH leads to condensation reactions, thus a change in the silica speciation.

18.
Eur J Health Econ ; 12(2): 127-40, 2011 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-20383553

RESUMO

This paper simulates the impact across household types of fully funded tax reforms designed to increase consumers' fiber intake from grain consumption. Our results suggest that household types with the highest initial consumption share of fiber-rich products--i.e., households without children (seniors, couples without children, and single women without children)--experience the highest increase in fiber intake from these reforms. However, they also experience high increases in unhealthy nutrients from the reforms, making the net health effects difficult to evaluate. Seniors and couples without children also gain most financially, paying less food taxes and facing, depending on the reform, either a lower price level than before the reform or a lower increase in the price level than the average household. These household types also face the lowest initial price level. Households with the lowest initial consumption share of fiber-rich products--families with children--appear to gain the least financially from the reforms: they pay more food taxes and face relatively high increases in price levels. Further, in general they experience an increase in fiber intake smaller than that of the average household. However, they do generally see reductions in the intake of added sugar, and in many cases saturated fat, which positively affects the health of families with children, who often overconsume these nutrients.


Assuntos
Dieta/economia , Dieta/estatística & dados numéricos , Políticas , Impostos/economia , Impostos/estatística & dados numéricos , Fibras na Dieta , Grão Comestível , Características da Família , Humanos , Fatores Socioeconômicos
19.
J Phys Chem A ; 114(50): 13146-53, 2010 Dec 23.
Artigo em Inglês | MEDLINE | ID: mdl-21114301

RESUMO

Synthetic imidazole ligands are typically substituted at the N(1) ((1)-Im) position while natural imidazole ligands are substituted at the C(4) ((4)-Im) position. To outline the difference in coordination properties, the methyl-substituted imidazoles Me(4)-Im and Me(1)-Im were complexed with CuCl(2) and ZnCl(2) and investigated by NMR relaxometry, electron paramagnetic resonance, far-Fourier transform IR vibrational spectroscopy, and ab initio calculations. Me(4)-Im, Me(1)-Im, and Im in excess form the usual tetragonal D(4h) [CuL(4)X(2)] complexes with CuCl(2) whereas the methylated imidazoles form pseudotetrahedral C(2v) complexes instead of the usual octahedral O(h) [ZnIm(6)](2+) complex. All imidazoles display a high degree of covalence in the M-L σ- and π-bonds and the π-interaction strength affects the relative energies of complexation. Opportunities to tailor complexes by the chemical properties of the substituents are envisaged due to the role of the inductive and hyperconjugative effects, rather than position.

20.
J Health Econ ; 28(3): 622-34, 2009 May.
Artigo em Inglês | MEDLINE | ID: mdl-19329203

RESUMO

In this paper, we simulate the effects of tax reforms aimed at encouraging healthier grain consumption. We use a rich data set on household grain consumption in 2003 from the market research institute GfK Sweden, combined with information on the nutritional content of the consumption. We estimate behavioral parameters, which are used to simulate the impact on the average household of tax reforms entailing either a subsidy on commodities particularly rich in fiber or a subsidy of the fiber density in grain products. Our results suggest that to direct the fiber intake towards nutritional recommendations, reforms with a substantial impact on consumer prices are required. Regardless of the type of subsidy implemented, the increase in the intake of fiber is accompanied by unwanted increases in nutrients that are often overconsumed: fat, salt and sugar. Funding the subsidies by taxing these nutrients, or less healthy commodities, helps to counteract such developments.


Assuntos
Grão Comestível , Comportamento Alimentar , Impostos , Comportamento de Escolha , Humanos , Modelos Econométricos
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