The degradation of cellulose in ionic mixture solutions under the high pressure of carbon dioxide.

This work aims to study the product characteristics of cellulose degradation not only by a hydrothermal process but also in combination with a sonication process. Herein, 4.3 mL of oxalic acid (H2C2O4)-sodium chloride (NaCl) solution containing cellulose was placed into a stainless steel reactor (or the mixture was placed into the reactor after the sonication process for 1 hour); then, carbon dioxide (CO2) was released for pressurization. Degradation was performed under certain pressures (70 and 200 bar) and temperatures (125 °C and 200 °C) at various times. Scanning Electron Microscopy (SEM) results indicated that the sonication pretreatment process affected the solid cellulose, making it rougher or fibrous than the non-sonicated process. XRD characterization results indicated that both process types caused changes in the crystallinity and composition of cellulose I and II with pressure, temperature, and time. The combination of sonication and hydrothermal processes resulted in lower crystallinity. Changes in crystallinity showed different characteristics in swelling, reduced the interaction between chains, and even broke the polymer chains inside the particles. In a hydrothermal process at 200 bar and 200 °C, a maximum reducing sugar concentration of 5.1 g L-1 was obtained, while 3.2 g L-1 was obtained in the combined sonication and hydrothermal process under the same operating condition, which is below the value attained at 200 °C and 70 bar. These results indicated the existing competition between the formation and further degradation of the reducing sugar, a phenomenon explained by the presence of a monomer (reducing sugar), an oligomer (cellotriose), and 5-HMF (5-hydroxymethyl-2-furaldehyde) in a liquid product processed under hydrothermal conditions.

Study of cassava starch degradation using sonication process in aqueous sodium chloride.

BACKGROUND: Starch degradation is an important process that can increase starch utilization in some industrial applications. In many polysaccharide compounds, the addition of salt is an alternative method to enhance the structural degradation of starch by sonication. This study aimed to investigate the effect of sonication in aqueous NaCl solution on the structural degradation of cassava starch. RESULTS: This method produces reducing sugar which its amount is relatively smaller than the amount of total dissolved solid product. The maximum total reducing sugar (TRS) was 0.365 ± 0.005 kg m-3 (or about 7.3 mg g-1 ) that resulted by S50 for 60 min reaction. The increase of sonication amplitude was in line with the increase of granule defect in SEM image. X-ray diffraction (XRD) showed that the degradation process was characterized by rupturing of the amorphous region. CONCLUSION: The structural alteration and the increase in NaCl weight suggest that this process may become a useful method for starch modification. © 2020 Society of Chemical Industry.