RESUMO
Chitosan (Ch) and zinc oxide nanoparticles loaded gallic-acid films, (Ch-ZnO@gal) have been prepared aiming for their exploitation as environmentally benign food packaging material. The chitosan films with varying quantities of zinc oxide nanoparticles loaded gallic-acid (ZnO@gal) content were synthesized in order to evaluate the effect of ZnO@gal on their optimum mechanical and biological potential. The characteristic results have shown that the incorporation of ZnO@gal into chitosan films remarkably enhanced the desired mechanical property of the chitosan films. Other noticeable physical properties such as oxygen and water vapor permeability (WVP), swelling, water solubility and UV-vis light transmittance have also been found to improve positively. SEM analysis of the films indicates a good material compatibility between chitosan and ZnO@gal matrices. Ch-ZnO@gal films possess significant antibacterial potential and strong antioxidant behavior compared to pristine chitosan. The overall results suggested that the prepared biocomposite chitosan films may be considered for active food packaging applications.
Assuntos
Quitosana/química , Embalagem de Alimentos/métodos , Ácido Gálico/química , Nanopartículas/química , Óxido de Zinco/química , Antibacterianos/química , Antioxidantes/química , Bacillus subtilis/efeitos dos fármacos , Materiais Biocompatíveis/química , Escherichia coli/efeitos dos fármacos , Embalagem de Alimentos/instrumentação , Permeabilidade , Solubilidade , Vapor , Resistência à Tração , Raios Ultravioleta , Óxido de Zinco/farmacologiaRESUMO
Ecofriendly chitosan-gelatin (Ch-ge) bio-composite films containing Quercetin-starch (Q) were synthesized using solution casting method. Physicochemical characteristics and mechanical properties of the resulting chitosan-gelatin containing Quercetin-starch films (Ch-ge-Q) were studied using UV, FTIR, XRD and SEM techniques. The films were also investigated for their swelling, water-vapor permeability (WVP), water solubility properties. The FTIR spectra confirmed the chemical interactions between the chitosan-gelatin and Q. Surface morphology of prepared film was analyzed by the SEM imaging while XRD spectra suggest the expanded crystallinity of the film with the addition of Q. The film also showed enhanced barrier property against UV rays. The reduction of water-vapor permeability and increase in tensile strength while a decrease in elongation at break has been observed in the Ch-ge-Q film compared to Ch-ge film. The antibacterial activity of Ch-ge-Q film against both gram positive (B. substilis) and gram negative (E. coli) bacteria suggested the Q loaded Ch-ge films as more feasible antibacterial candidate especially against the strain E. coli. The antioxidant activity of the Ch-ge-Q film was evaluated using the DPPH and ABTS as standards and corresponded to 81.45% of DPPH and 72.2% of ABTS scavenging activities. It was observed that the film containing Quercetin-starch presented superior antioxidant activity results in comparison to Ch-ge film promising its application in food packaging.