RESUMO
Flexible, large-area, and low-cost thermal sensing networks with high spatial and temporal resolution are of profound importance in addressing the increasing needs for industrial processing, medical diagnosis, and military defense. Here, a thermoelectric (TE) fiber is fabricated by thermally codrawing a macroscopic preform containing a semiconducting glass core and a polymer cladding to deliver thermal sensor functionalities at fiber-optic length scales, flexibility, and uniformity. The resulting TE fiber sensor operates in a wide temperature range with high thermal detection sensitivity and accuracy, while offering ultraflexibility with the bending curvature radius below 2.5 mm. Additionally, a single TE fiber can either sense the spot temperature variation or locate the heat/cold spot on the fiber. As a proof of concept, a two-dimensional 3 × 3 fiber array is woven into a textile to simultaneously detect the temperature distribution and the position of heat/cold source with the spatial resolution of millimeter. Achieving this may lead to the realization of large-area, flexible, and wearable temperature sensing fabrics for wearable electronics and advanced artificial intelligence applications.
RESUMO
Asymmetry parameters of the electric field gradient tensor at (75) As nuclei were determined for chalcogenide glassy semiconductors (CGS) of the Ge-As-Se system by comparing the experimental and simulated (75) As nuclear quadrupole resonance nutation interferograms. The electric field gradient asymmetry in CGS was analyzed, and it is believed that a structural change in these glassy semiconductors takes place at r¯ = 2.425. Electron paramagnetic resonance spectra of the Ge-As-Se system were obtained for the first time. A comparison was made between the results of analysis of the Ge-As-Se system by nuclear quadrupole resonance and electron paramagnetic resonance methods, and this allowed us to make the supposition that a structural phase transition occurs at r¯ = 2.4 from two-dimensional to three-dimensional CGS structure.